[PokeMMO Comp Guide] Pokémon Effort Values (EVs)
As Pokémon battle, in addition to gaining experience points they also obtain Effort Values (usually referred to as EVs), which are special values (which are hidden in the original games) in each stat (HP, Attack and so on). Each Pokémon you battle against gives off EVs in one or more stats.
Generally, this relates to the Pokémon's strongest stat - for example, if you battle a Geodude your Pokémon will get one EV in the Defense stat. If you fight a Gengar, you will get three Special Attack EVs. (See the pages to the left to see which Pokémon give off which EVs.)
Newly-hatched eggs and Pokémon caught in the wild - regardless of level - have no EVs and thus act as a blank sheet for EV training. Any Pokémon that has gained experience points from battling will have gained some EVs.
Every 4 EVs obtained in a particular stat equals one more point for that stat, by the time that Pokémon reaches level 100. At low levels you may not see all the points added straight away. If your Pokémon is at a high level you will see a lot of additional points going on to the appropriate stats at each level up.
In total a Pokémon can gain 510 EVs, but only 255 in one stat. Since 4 EVs equals one stat point, if you want to max out a particular stat it's only useful to get 252 EVs (63 points). The last 3 EVs would be wasted. However, in practice it's a chore to count exactly how many EVs you have obtained (there's no other way to tell) so you may wish to simply max out a particular stat and forego a point or two.
EV-boosting items
Battling 252 Bidoofs to max out your HP would be a bit of a bore, no? Luckily, there is an array of items that can help you reach your goal much quicker.
Vitamins
These items, purchaseable from the big department store in each game (Veilstone/Lilycove/Golenrod/Celadon), give your Pokémon 10 EVs in the corresponding stat. Vitamins are not affected by any of the other items below.
The vitamins are as follows:
Macho Brace
The Macho Brace lowers a Pokémon's speed in battle while held, but doubles the amount of EVs gained. A Starly normally provides 1 Speed EV, but with your Pokémon holding the Macho Brace, it will receive 2 Speed EVs.
Exp. Share
Since any Pokémon gaining experience points gains EVs, the Exp. Share item allows Pokémon to gain EVs without battling. It will gain the same base EVs that the Pokémon in battle gains.
EV-reducing berries
There are also a set of berries that will reduce your Pokémon's EVs. They are useful if you miscount EVs or simply want to change the EV distribution.
If you have over 100 EVs in a stat, the first berry will reduce them to 100, while further berries will decrease the EVs by 10. Therefore if you want to remove all EVs you will need 11 berries for the stat.
Credits: https://pokemondb.net/ev
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